코스넷:::::화장품원료:::::

 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Dictyocarpine

다른이름들 

6-Acetyldictyocarpinine

함유 천연물 

Abrus cantoniensis Hance[-]()

분 자 식 

C₂₆H₃₉NO₈

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

493.603

녹 는 점 

214.5-216.5°C Hexane/Me2CO

굴 절 율 

[α]24 D = -14.7° (C 0.97,CHCl3)

HNMR_CHART 

(CDCl3,60 MHz) δ:0.88(3H,s,Me-4), 1.08(3H,t,NCH2CH3), 2.12(3H,s,OOCCH3), 3.30 and 3.39(ea.3H,s,OMe), 4.70(1H,dd,6,6,H14beta), 5.00 and 5.05(ea.1H,s,OCH2O), 5.55(1H,d,1.5,H6alpha)

CNMR_CHART 

(CDCl3,15.03 MHz) δ: 78.7, 26.4, 37.6, 34.0, 51.8, 77.2, 93.0, 82.9, 50.4, 79.9, 55.1, 36.5, 36.6, 72.8, 32.9, 81.2, 64.4, 25.5, 56.9, 50.4, 14.0, 55.6, 94.0, 56.3, 170.2, 21.8

참고문헌 

· SW. Pelletier et al., J. Org. Chem., 46, 3284, 1981 · JD. Olsen et al., Phytochemistry, 28, 5, 1521, 1989 · MS. Rabinovich et al., Zh. Obshch. Khim., 22, 1702, 1952 · AS. Narzullaev et al., Khim. Prir. Soedin., 8, 498, 1972; 9, 443, 1973; Chem. Nat. Compd. (Engl. Transl.), 8, 491, 1972; 9, 424, 1973 · BT. Salimov et al., Khim. Prir. Soedin., 13, 128, 1977; 14, 235, 1978; Chem. Nat. Compd. (Engl. Transl.), 13, 120, 1977; 14, 194, 1978 · SW. Pelletier et al., Can. J. Chem., 58, 1875, 1980 · MG. Zhamierashvili et al., Khim. Prir. Soedin., 16, 663, 1980; Chem. Nat. Compd. (Engl. Transl.), 16, 479, 1980 · SW. Pelletier et al., J. Am. Chem. Soc., 103, 6536, 1981 · J. Finer-Moore et al., J. Org. Chem., 46, 3399, 1981 · BT. Salimov et al., Khim. Prir. Soedin., 530, 1981; CA, 96, 100872m · OE. Edwards et al., Can. J. Chem., 60, 2661, 1982 · SW. Pelletier et al., J. Nat. Prod., 47, 643, 1984 · SW. Pelletier et al., Heterocycles, 23, 331, 1985 · VM. Matveev et al., Khim. Prir. Soedin., 21, 131, 1985; Chem. Nat. Compd. (Engl. Transl.), 21, 133, 1985 · AS. Narzullaev et al., Khim. Prir. Soedin., 24, 396, 1988; Chem. Nat. Compd. (Engl. Transl.), 24, 335, 1988 · SW. Pelletier et al., Tetrahedron, 45, 1887, 1989