코스넷:::::화장품원료:::::

 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

Browniine

함유 천연물 

Abrus cantoniensis Hance[-]()

분 자 식 

C₂₅H₄₁NO₇

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

467.608

녹 는 점 

amoph. 211.5-213.0°C

굴 절 율 

[α]25 D = +40.2° (C 2.5,EtOH)

HNMR_CHART 

(CDCl3) δ:1.04(3H,s,NCH2CH3), 3.24, 3.30, 3.36, 3.40(ea.3H,s,OCH3)

CNMR_CHART 

(CDCl3,15 MHz) δ: 85.2, 25.5, 32.5, 38.4, 45.1, 90.1, 89.1, 76.3, 49.6, 36.4, 48.2, 27.5, 46.1, 75.3, 33.1, 81.7, 65.4, 78.0, 52.7, 51.3, 14.3, 56.0, 57.5, 56.5, 59.1

참고문헌 

· SW. Pelletier et al., J. Nat. Prod., 43, 395, 1980; 47, 643, 1984 · JD. Olsen et al., Phytochemistry, 28, 5, 1521, 1989 · MH. Benn et al., Can. J. Chem., 41, 477, 1963 · MH. Benn, Can. J. Chem., 44, 1, 1966 · AJ. Jones et al., Can. J. Chem., 51, 486, 1973(cmr) · SW. Pelletier et al., Heterocycles, 7, 327, 1977 · VG. Kazlikhin et al., Khim. Prir. Soedin., 13, 869, 1977; Chem. Nat. Compd. (Engl. Transl.), 13, 737, 1977 · BT. Salimov et al., Khim. Prir. Soedin., 14, 106, 1978; Chem. Nat. Compd. (Engl. Transl.), 14, 84, 1978 · VN. Aiyar et al., Phytochemistry, 17, 1453, 1978 · SW. Pelletier et al., Can. J. Chem., 57, 1652, 1979(cmr) · SW. Pelletier et al., J. Org. Chem., 46, 3284, 1981 · OE. Edwards et al., Can. J. Chem., 60, 2661, 1982 · S. Sakai et al., Yakugaku Zasshi, 104, 222, 1984; CA, 101, 69329k · P. Kulanthaivel et al., Heterocycles, 27, 339, 1988 · K. Wada et al., Heterocycles, 29, 2141, 1989