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 ▣ 천연물에서 분리된 개별유효성분 레코드 등록정보

성 분 명 

N-Acetylcytisine((-)-form)

다른이름들 

(-)-1,2,3,4,5,6-Hexahydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazocin-8-one; N-Ac (-)-Baptitoxine; N-Ac (-)- Citisine; N-Ac (-)-Cytiton; N-Ac (-)-Sophorine; N-Ac (-)-Ulexine; N-Ac

함유 천연물 

Sophora secundiflora (Ortega) Lag.ex DC.[]()
Sophora tomentosa L.[-]()

분 자 식 

C₁₃H₁₆N₂O₂

화학족 분류 

알칼로이드(alkaloid);

분 자 량 

232.285

녹 는 점 

210-213°C

굴 절 율 

[α]26 D = -208° (C 0.182,EtOH)

MASS_CHART 

GCM+= 232, m/z= 190, 160, 147, 146(100), 134, 108, 82, 44(100), 43

참고문헌 

· H. Kubo et al., Phytochemistry, 25, 8, 2000, 1986 · H. Otomasu et al., Phytochemistry, 13, 1016, 1974(ir); 20, 1725, 1981 · S. Yu et al., Khim. Prir. Soedin., 6, 276, 1970; CA, 73, 45650, K · PI. Chavez et al., Diss. Abstr. Int. B, 42, 2626, 1982 · HR. Ing et al., J. Chem. Soc., 2195, 1931 · F. Bohlmann et al., Chem. Ber., 89, 792, 1956(uv,ir); 108, 1043, 1975(cmr) · PC. Ruenitz et al., J. Het. Chem., 14, 423, 1977(ms) · T. Satoshi et al., Phytochemistry, 30, 11, 3793, 1991(cmr) · Aldrich Library of 13C and 1H FT NMR Spectra, 1, 1324B (nmr) · HR. Ing, J. Chem. Soc., 2195, 1931; 2778, 1932 · WF. Cockburn et al., Can. J. Chem., 30, 92, 1952 · TT. Shakirov et al., Khim. Prir. Soedin., 6, 723, 1970; Chem. Nat. Compd. (Engl. Transl.), 6, 733, 1970 · AI. Ishbaev et al., Khim. Prir. Soedin., 8, 328, 1972; Chem. Nat. Compd. (Engl. Transl.), 8, 322, 1972 · TE. Monakhova et al., Khim. Prir. Soedin., 9, 59, 1973; Chem. Nat. Compd. (Engl. Transl.), 9, 52, 1973 · I. Murakoshi et al., Phytochemistry, 16, 1460, 1977; 21, 1470, 2385, 1982 · AA. Freer et al., Acta Cryst. C, 43, 1119, 1987 · R. Greinwald et al., Phytochemistry, 29, 3553, 1990 · K. Saito et al., Tennen Yuki Kagobutsu Toronkai Koen Yoshishu , 32, 268, 1990 · R. Greinwald et al., Z. Naturforsch., C, 45, 1085, 1990 · AM. Gazaliev et al., Khim. Prir. Soedin., 27, 301, 1991; Chem. Nat. Compd. (Engl. Transl.), 27, 259, 1991 · G. Veen et al., Phytochemistry, 31, 3487, 1992 · Martindale, The Extra Pharmacopoeia, 30th edn., Pharmaceutical Press, London, 12886, 1993